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Title:

Impact of flavouring substances on the aggregation behaviour of dissolved barley β-glucans in a model beer

Document type:
Zeitschriftenaufsatz
Author(s):
Kupetz, M.; Sacher, B.; Becker, T.
Abstract:
Structural polymers such as cereal β-glucan may cause various processing problems in beverage industry depending on concentration, molar size distribution and agglomeration behaviour. In this context, influences of the beer volatiles dodecanoic acid, octyl butanoate, ethyl decanoate and decyl acetate on molar mass and radii of barley β-glucan were investigated in ethanolic (4% w/w) model solution. After addition of 100mg/l ethyl decanoate and decyl acetate to the β-glucan solution, a wider-ranging molar mass distribution could be observed by means of asymmetric field-flow-fractionation. Due to agglomeration, average molar mass of β-glucan standard (MW=6.8×106g/mol) increased by 2×106g/mol (P<0.05) in solution containing decyl acetate. Furthermore, a significant growth (P<0.05) from 86 to 102nm in gyration radius was measured. The obtained results elucidate the importance of fatty acid derived flavouring substance composition in beer regarding the aggregation behaviour of β-glucan.
Keywords:
Hydrocolloid Viscosity Beer Molar mass Asymmetric flow-field-flow-fractionation
Journal title:
Carbohydrate Polymers
Year:
2016
Journal volume:
143
Pages contribution:
204-211
Fulltext / DOI:
doi:10.1016/j.carbpol.2016.01.070
WWW:
http://www.sciencedirect.com/science/article/pii/S0144861716300340
Print-ISSN:
0144-8617
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