The present work describes the preparation and structural characterization of molecular vanadium compounds, supported on oxide and fluoride surfaces (single-site catalysts) as model systems for heterogeneous catalysts. The vanadium systems were structurally characterized before and after their use in catalysis. Electron paramagnetic resonance (EPR), double resonance and pulsed techniques (ENDOR, ESEEM and HYSCORE) allowed detailed insight into structure and reactivity of the vanadium complexes on solids and in solution. The molecular vanadium catalyst systems showed interesting features in the ODH of propane.
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The present work describes the preparation and structural characterization of molecular vanadium compounds, supported on oxide and fluoride surfaces (single-site catalysts) as model systems for heterogeneous catalysts. The vanadium systems were structurally characterized before and after their use in catalysis. Electron paramagnetic resonance (EPR), double resonance and pulsed techniques (ENDOR, ESEEM and HYSCORE) allowed detailed insight into structure and reactivity of the vanadium complexes o...
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