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Titel:

Nanocylindrical confinement imparts highest structural order in molecular self-assembly

Dokumenttyp:
Zeitschriftenaufsatz
Autor(en):
Pathak, A.; Bora, A.; Braunschweig, B.; Meltzer, C.; Yan, H.; Lemmens, P.; Daum, W.; Schwartz, J.; Tornow, M.
Abstract:
We report the impact of geometrical constraint on intramolecular interactions in self-assembled monolayers (SAMs) of alkylphosphonates grown on anodically oxidized aluminum (AAO). Molecular order in these films was determined by sum frequency generation (SFG) spectroscopy, a more sensitive measure of order than infrared absorption spectroscopy. Using SFG we show that films grown on AAO are, within detection limits, nearly perfectly ordered in an all-trans alkyl chain configuration. In marked con...     »
Zeitschriftentitel:
Nanoscale, 2017,9, 6291-6295 2017-05
Jahr:
2017
Jahr / Monat:
2017-05
Quartal:
2. Quartal
Monat:
May
Sprache:
en
Volltext / DOI:
doi:10.1039/C7NR02420G
WWW:
https://pubs.rsc.org/en/content/articlelanding/2017/nr/c7nr02420g
Verlag / Institution:
Royal Society of Chemistry RSC
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