The dissertation deals with the mineralizer controlled formation and characterization of new polyphosphides compounds [Au_2.49In_1.51]AuP₁₀, Li_0.2CdP₂, α' CdP2, LiP15 and of single phase fibrous phosphorus. The characterization of the structures and of the features were examined by X ray diffraction experiments, by quantum chemical investigations, by IR and Raman spectroscopy, by solid state NMR spectroscopy, by thermal and electrochemical measurements. Li_0.2CdP₂ shows the highest observed Li ion mobility of all solid lithium ion conductors.     «

The dissertation deals with the mineralizer controlled formation and characterization of new polyphosphides compounds [Au_2.49In_1.51]AuP₁₀, Li_0.2CdP₂, α' CdP2, LiP15 and of single phase fibrous phosphorus. The characterization of the structures and of the features were examined by X ray diffraction experiments, by quantum chemical investigations, by IR and Raman spectroscopy, by solid state NMR spectroscopy, by thermal and electrochemical measurements. Li_0.2CdP₂ shows the highest observed Li ion...     »