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Titel:

Infrared Spectroscopy of Gas-Phase M+(CO2)n (M = Co, Rh, Ir) Ion–Molecule Complexes

Dokumenttyp:
Zeitschriftenaufsatz
Autor(en):
Iskra, Andreas; Gentleman, Alexander S.; Kartouzian, Aras; Kent, Michael J.; Sharp, Alastair P.; Mackenzie, Stuart R.
Abstract:
The structures of gas-phase M+(CO2)n (M = Co, Rh, Ir; n = 2–15) ion–molecule complexes have been investigated using a combination of infrared resonance-enhanced photodissociation (IR-REPD) spectroscopy and density functional theory. The results provide insight into fundamental metal ion–CO2 interactions, highlighting the trends with increasing ligand number and with different group 9 ions. Spectra have been recorded in the region of the CO2 asymmetric stretch around 2350 cm–1 using the inert me...     »
Zeitschriftentitel:
The Journal of Physical Chemistry A
Jahr:
2016
Band / Volume:
121
Jahr / Monat:
2016-12
Quartal:
4. Quartal
Monat:
Dec
Heft / Issue:
1
Seitenangaben Beitrag:
133-140
Volltext / DOI:
doi:10.1021/acs.jpca.6b10902
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