Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions
Abstract:
A chiral Mn(salen)complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.
Kongresstitel:
ISI Document Delivery No.: 713VX Times Cited: 5 Cited Reference Count: 51 Voss, Felix Herdtweck, Eberhardt Bach, Thorsten Deutsche Forschungsgemeinschaft [Ba 1372-10]; Fonds der Chemischen Industrie This project was supported in part by the Deutsche Forschungsgemeinschaft (Ba 1372-10) and by the Fonds der Chemischen Industrie. 5 Royal soc chemistry Cambridge