Epoxidation in ionic liquids: A comparison of rhenium(VII) and molybdenum(VI) catalysts

Complexes of the type (dimethyl-bpy) MoO(2)Cl(2) and Schiff/Lewis-base complexes of methyltrioxorhenium (MTO), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined with respect to their catalytic performance at 55 and 25 degrees C in systems employing room temperature ionic liquids (RTILs) of composition [BMIM] NTf(2), [BMIM]PF(6), [BMIM] BF(4) and [C(8)MIM] PF(6) as solvents. The performance in the cyclooctene epoxidation was observed to be strongly dependent on the water content of the system and the catalyst solubility in the RTIL. MTO based systems prove to be superior with respect to lower energy consumption, higher stability and higher product yields compared to the investigated Mo(VI)system under the conditions applied. (C) 2009 Elsevier B.V. All rights reserved.     «

Complexes of the type (dimethyl-bpy) MoO(2)Cl(2) and Schiff/Lewis-base complexes of methyltrioxorhenium (MTO), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined with respect to their catalytic performance at 55 and 25 degrees C in systems employing room temperature ionic liquids (RTILs) of composition [BMIM] NTf(2), [BMIM]PF(6), [BMIM] BF(4) and [C(8)MIM] PF(6) as solvents. The performance in the cyclooctene epoxidation was observed to be strongly dependent...     »