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Title:

Chiral N-heterocyclic biscarbenes based on 1,2,4-triazole as ligands for metal-catalyzed asymmetric synthesis

Document type:
Journal Article
Author(s):
Riederer, S. K. U.; Bechlars, B.; Herrmann, W. A.; Kuhn, F. E.
Abstract:
A facile and straightforward synthetic procedure for the preparation of new chiral bis-1,2,4-triazolium salts and their corresponding rhodium(I) biscarbene complexes are reported. It is widely applicable for the synthesis of 1,2,4-triazolium salts. The new chiral biscarbenes represent promising ligands for transition metal-catalyzed asymmetric syntheses. Their first successful application is demonstrated by the rhodium-catalyzed hydrogenation of dimethylitaconate and methyl-2-acetamidoacrylate w...     »
Congress title:
ISI Document Delivery No.: 697YV Times Cited: 7 Cited Reference Count: 33 Riederer, Stephanie K. U. Bechlars, Bettina Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Margarete Ammon Stiftung This work was generously supported by the Margarete Ammon Stiftung (Ph.D. grant for S.K.U.R). 7 Royal soc chemistry Cambridge
Journal title:
Dalton Transactions
Year:
2011
Journal volume:
40
Journal issue:
1
Pages contribution:
41-43
Fulltext / DOI:
doi:10.1039/c0dt00724b
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