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Title:

Orientational changes of supported chiral 2,2[prime or minute]-dihydroxy-1,1[prime or minute]binaphthyl molecules

Author(s):
Heister, Philipp; Lunskens, Tobias; Thamer, Martin; Kartouzian, Aras; Gerlach, Sabine; Verbiest, Thierry; Heiz, Ueli
Abstract:
Well defined thin molecular films of 2,2[prime or minute]-dihydroxy-1,1[prime or minute]binaphthyl (binol) molecules at coverages between 5 [times] 1015 molecules per cm2 and 1017 molecules per cm2 on thin glass (BK7) substrates were investigated under ultra-high-vacuum (UHV) conditions. Second-Harmonic-Generation Optical-Rotatory-Dispersion measurements (SHG-ORD) were performed using a dedicated spectroscopic setup which allows for the determination of the rotation angle of the SH-signal of two...     »
Journal title:
Phys. Chem. Chem. Phys.
Year:
2014
Fulltext / DOI:
doi:10.1039/C4CP00106K
Publisher:
The Royal Society of Chemistry
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