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Title:

Microkinetic simulations of the oxidation of CO on Pd based nanocatalysis: a model including co-dependent support interactions

Author(s):
Harding, C. J.; Kunz, Sebastian; Habibpour, Vahideh; Heiz, Ulrich
Abstract:
The catalysed oxidation of CO using mass-selected Pd(13) clusters supported on thin MgO films was modelled using a microkinetic simulation of the reaction. The model of the system includes reverse spill-over calculations which were intrinsically incorporated into the formulation of the kinetics. The spill-over model is based on a capture-zone approach including a co-dependence on the variables of the kinetic equations. The experimental values were determined using dual pulsed-molecular beam meas...     »
Congress title:
Lehrstuhl fur Physikalische Chemie, Technische Universitat Munchen, Garching, Germany. 1463-9076 FIELD Electronic Internat.Standard Doc. Number: England: United Kingdom Journal; Article; (JOURNAL ARTICLE); (RESEARCH SUPPORT, NON-U.S. GOV'T)
Journal title:
Phys Chem Chem Phys
Year:
2008
Journal volume:
10
Journal issue:
38
Pages contribution:
5875-81
Fulltext / DOI:
doi:10.1039/b805688a
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