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Title:

The weakly-bound complex Cl.N2O studied by high resolution photodetachment photoelectron spectroscopy

Author(s):
Boesl, Ulrich; Distelrath, Volker; Selzle, Heinrich
Abstract:
Zero kinetic energy photoelectron spectroscopy of the weakly bound complex Cl(-).N(2)O is presented. Adiabatic detachment energies between the anionic complex and the neutral complex states X(1/2), I(3/2), and II(1/2) as well as frequencies of van der Waals modes are supplied. Supported by theoretical simulations, these results correlate with a T-shaped structure of the anionic and an L-shaped structure of the neutral molecular complex. The weakly bound neutral complex Cl.N(2)O has been discusse...     »
Keywords:
Anions *Chlorides: CH, chemistry Electrons Hydrogen Bonding Kinetics Mathematics Models, Molecular *Nitrogen Oxides: CH, chemistry *Nitrous Oxide: CH, chemistry Spectrum Analysis Thermodynamics 0 (Anions) 0 (Chlorides) 0 (Nitrogen Oxides)
Congress title:
Physical Chemistry, Chemistry Department, Technical University Munich, Garching, Germany. 1463-9076 FIELD Electronic Internat.Standard Doc. Number: England: United Kingdom Journal; Article; (JOURNAL ARTICLE) 10024-97-2 (Nitrous Oxide)
Journal title:
Phys Chem Chem Phys
Year:
2008
Journal volume:
10
Journal issue:
41
Pages contribution:
6252-7
Fulltext / DOI:
doi:10.1039/b807992g
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