Within this work, a solution-based approach to inverse opal structured Si/Ge thin films ultilizing intermetallic phases containing well-defined atom clusters was investigated. Additionally, porous Sn/Bi thin films could be obtained. Solubility in common laboratory solvents and therefore accessibility of nine atomic Si/Ge clusters was enhanced by introduction of silyl ligands and NHC stabilized coinage metal complexes to the clusters. The resulting compounds were tested as new precursors for the solution-based fabrication of thin films of semiconducting materials.
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Within this work, a solution-based approach to inverse opal structured Si/Ge thin films ultilizing intermetallic phases containing well-defined atom clusters was investigated. Additionally, porous Sn/Bi thin films could be obtained. Solubility in common laboratory solvents and therefore accessibility of nine atomic Si/Ge clusters was enhanced by introduction of silyl ligands and NHC stabilized coinage metal complexes to the clusters. The resulting compounds were tested as new precursors for the...
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