The design space of possible metal-organic framework (MOF) structures is vast, but void of good electrical conductors. We investigate one of the few known prime examples, iron(II) triazolate, and various modifications to find the underlying reasons for this. An improved version of the simple and well-known Bardeen-Shockley model thereby helps us to understand how such changes affect the charge carrier mobility and its underlying material properties to orient towards MOFs with even higher carrier mobility in the future.
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The design space of possible metal-organic framework (MOF) structures is vast, but void of good electrical conductors. We investigate one of the few known prime examples, iron(II) triazolate, and various modifications to find the underlying reasons for this. An improved version of the simple and well-known Bardeen-Shockley model thereby helps us to understand how such changes affect the charge carrier mobility and its underlying material properties to orient towards MOFs with even higher carrier...
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