Detailed kinetic and mechanistic analysis of activated carbons enabled the development of highly stable and selective functional catalysts for transient phosgene synthesis. Employing advanced spectroscopic techniques, various in situ formed crucial intermediates for phosgene production were identified and their involvement in different catalytic steps has been studied in detail. By careful selection of probe molecules, the electronic nature of reactive intermediates were differentiated. Alumina has been successfully identified as new selective and stable catalyst through these studies.
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Detailed kinetic and mechanistic analysis of activated carbons enabled the development of highly stable and selective functional catalysts for transient phosgene synthesis. Employing advanced spectroscopic techniques, various in situ formed crucial intermediates for phosgene production were identified and their involvement in different catalytic steps has been studied in detail. By careful selection of probe molecules, the electronic nature of reactive intermediates were differentiated. Alumina...
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