Investigating the role of moisture on concrete carbonation using single-sided 1H-NMR

Accelerated test methods are commonly used in order to predict concrete carbonation in natural concentrations. Here, specimens are carbonated at high CO2 concentrations at a specified temperature and relative humidity. However, the transfer of laboratory results to field behaviour remains difficult because CO2 transport is affected by the original moisture content of the specimens and additional moisture formed by the carbonation reaction. Therefore knowledge on moisture transport and content during carbonation is required. Specimens made with Ordinary Portland cement and a water/cement ratio 0.50 were exposed to 0.05, 2 and 10 vol.% CO2 for 28 days. Single-sided NMR moisture profiles were determined before, during and after carbonation. It is shown that moisture content increases due to carbonation at high CO2 concentrations (≥ 10 %) in the beginning of the exposure. An increase in capillary pore water in front and behind the carbonation front could be observed even after 28d. During natural carbonation moisture changes are mainly due to the change in porosity produced by the carbonation reactions. It is shown that changes in phase composition and thus porosity dominate the carbonation process in cement-based materials. Therefore, the suitability of high CO2 concentrations is limited for an accelerated test that reflects field condition. Single-sided 1H NMR proved to be a valuable tool to investigate moisture transport in concrete non-destructively.      «

Accelerated test methods are commonly used in order to predict concrete carbonation in natural concentrations. Here, specimens are carbonated at high CO2 concentrations at a specified temperature and relative humidity. However, the transfer of laboratory results to field behaviour remains difficult because CO2 transport is affected by the original moisture content of the specimens and additional moisture formed by the carbonation reaction. Therefore knowledge on moisture transport and content du...     »