Dicarboxylate-bridged (Mo-2)(n) (n=2, 3, 4) paddle-wheel complexes: potential intermediate building blocks for metal-organic frameworks

Koberl, M.; Cokoja, M.; Bechlars, B.; Herdtweck, E.; Kuhn, F. E.

doi:10.1039/c1dt11249j

Document type:: Journal Article
Author(s):: Koberl, M.; Cokoja, M.; Bechlars, B.; Herdtweck, E.; Kuhn, F. E.
Title:: Dicarboxylate-bridged (Mo-2)(n) (n=2, 3, 4) paddle-wheel complexes: potential intermediate building blocks for metal-organic frameworks
Abstract:: The treatment of the dimeric paddle-wheel (PW) compound [Mo-2(NCCH3)(10)][BF4](4) 1 with oxalic acid (0.5 equiv.), 1,1-cyclobutanedicarboxylic acid (1 equiv.), 5-hydroxyisophthalic acid (1 equiv.) (m-bdc-OH) or 2,3,5,6-tetrafluoroterephthalic acid (0.5 or 1 equiv.) leads to the formation of macromolecular dicarboxylate-linked (Mo-2)(n) entities (
Congress title:: ISI Document Delivery No.: 837LH Times Cited: 2 Cited Reference Count: 33 Koeberl, Mathias Cokoja, Mirza Bechlars, Bettina Herdtweck, Eberhardt Kuehn, Fritz E. Cokoja, Mirza/B-6906-2009; Kuhn, Fritz/A-3113-2010 TUM Graduate School M. K. acknowledges financial support of TUM Graduate School. The authors thank Johannes Wandt and Stephanie Weicker for their valuable help in experiments. 2 Royal soc chemistry Cambridge
Journal title:: Dalton Transactions
Year:: 2011
Journal volume:: 40
Journal issue:: 43
Pages contribution:: 11490-11496
Fulltext / DOI:: doi:10.1039/c1dt11249j
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