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Original title:
Wirkmechanismus verschiedener Celluloseether als Wasserretentionsmittel in der Tiefbohrzementierung und in Trockenmörtelsystemen
Translated title:
Working mechanism of various cellulose ethers as water retention admixtures in oil well cementing and in dry-mix mortar systems
Author:
Bülichen, Daniel
Year:
2013
Document type:
Dissertation
Faculty/School:
Fakultät für Chemie
Advisor:
Plank, Johann Peter (Prof. Dr.)
Referee:
Plank, Johann Peter (Prof. Dr.); Zollfrank, Cordt (Prof. Dr.)
Language:
de
Subject group:
CHE Chemie
Controlled terms:
Retentionsmittel; Celluloseether
TUM classification:
BAU 302d
Abstract:
Celluloseether als Additive zur Wasserrückhaltung wurden auf ihre Wirkmechanismen untersucht. Es wird zwischen bis 120 °C stabilen HECs und CMHECs für die Tiefbohrzementierung sowie den bis ~ 60 °C löslichen MCs für Baustoffsysteme unterschieden. Des Weiteren wurde der Einfluss eines erhöhten Sulfatgehalts in Gipsputz auf die Wirksamkeit von MC geprüft. Die Kernaussage der Studie ist, dass der Wirkmechanismus aller Celluloseether ab einer kritischen Konzentration auf einer Verengung oder Verstop...     »
Translated abstract:
The working mechanism of cellulose ethers as water retention agents was investigated. Due to temperature stability of HEC and CMHEC up to 120 °C and ~ 60 °C for MC, a differentiation between additives for oil well cementing and admixtures in building systems was made. Additionally, the influence of higher sulfate content present in CaSO4 binder systems on MC was probed. Generally, above the ”overlapping concentration”, the mechanism of cellulose ethers as water retention agents is based on physical plugging or narrowing of filter cake pores which form under pressure or at highly absorbent surfaces. The cellulose ethers associate into 3D polymer networks. At lower concentrations, however, the polymers behave differently. Highly anionic derivates such as CMHEC adsorb, while MC exhibited strong intramolecular water sorption. Furthermore, it was found that the water retention capacity MHPC decreased significantly in a CaSO4 binder system.
WWW:
https://mediatum.ub.tum.de/?id=1128410
Date of submission:
02.01.2013
Oral examination:
22.02.2013
File size:
4740338 bytes
Pages:
120
Urn (citeable URL):
https://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:91-diss-20130222-1128410-0-3
Last change:
05.04.2013
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