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Titel:

NO Monomers on MgO Powders and Thin Films

Autor(en):
Di Valentin, Cristiana; Pacchioni, Gianfranco; Chiesa, Mario; Giamello, Elio; Abbet, Stephane; Heiz, Ueli
Abstract:
The interaction of nitric oxide with the surface of MgO at low temp. was studied exptl. and theor. High-surface-area polycryst. MgO prepd. by CVD was exposed to both 14NO and 15NO and the corresponding adsorption complexes were monitored by ESR (EPR) spectra. MgO(100) thin films grown on Mo(100) in UHV conditions were exposed to 15NO and the adsorption products were studied by thermal desorption (TDS) and FTIR spectroscopies. The structure and properties of NO/MgO(100) were studied by cluster mo...     »
Stichworte:
Adsorbed substances Chemisorbed substances Chemisorption Physisorption (adsorption of NO on MgO powders and thin films) Isotope effect (in EPR of NO adsorbed on MgO powders and thin films) ESR IR spectra (of NO adsorbed on MgO powders and thin films) Desorption (thermal of NO adsorbed on MgO powders and thin films) nitric oxide adsorption magnesia powder film
Kongresstitel:
CAN 136:268607 66-3 Surface Chemistry and Colloids Dipartimento di Scienza dei Materiali, Universita di Milano-Bicocca, and Istituto Nazionale per la Fisica della Materia, Milan, Italy. Journal 1089-5647 1309-48-4 (Magnesium oxide (MgO)); 10102-43-9 (Nitrogen oxide (NO)) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PRP (Properties), PYP (Physical process), PROC (Process) (adsorption of NO on MgO powders and thin films); 10024-97-2 (Nitrogen oxide (N2O)); 1250...     »
Zeitschriftentitel:
J. Phys. Chem. B
Jahr:
2002
Band / Volume:
106
Heft / Issue:
7
Seitenangaben Beitrag:
1637-1645
Volltext / DOI:
doi:10.1021/jp0127770
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