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Titel:

Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy

Dokumenttyp:
Zeitschriftenaufsatz
Autor(en):
Ketkov, Sergey Y.; Selzle, Heinrich L.; Cloke, F. Geoffrey N.
Abstract:
It's a gas! Mass-analyzed threshold ionization (MATI) spectroscopy provides high-resoln. ionization potentials and low-energy vibrational frequencies of individual conformers of jet-cooled [(η6-PhMe)2Cr]. The signals arising from distinct structural isomers were identified from DFT calcns. and comparison of the [(η6-PhMe)2Cr] and [(η6-1,3-Me2C6H4)(η6-PhH)Cr] spectra (see picture). [on SciFinder(R)]
Stichworte:
Ionization potential Spectroscopy (direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy) Isomers (rotational direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy) bisarenechromium gaseous rotational isomer mass analyzed threshold ionization spectroscopy
Kongresstitel:
CAN 148:23399 80-5 Organic Analytical Chemistry G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia. Journal 1433-7851 33505-50-9 Role: ANT (Analyte), PRP (Properties), ANST (Analytical study) (confomers; direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy); 957763-22-3P Role: ANT (Analyte), PRP (Properties), SPN (Synthetic preparation), ANST (Analytical study), PREP...     »
Zeitschriftentitel:
Angew. Chem., Int. Ed.
Jahr:
2007
Band / Volume:
46
Heft / Issue:
37
Seitenangaben Beitrag:
7072-7074
Volltext / DOI:
doi:10.1002/anie.200702233
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