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Original title:
Neue Oligomerisierungsphänomene in der Gold(I)-Chemie am Beispiel der (Phosphan)Gold-Komplexe
Translated title:
New Oligomerisation Phenomena in Gold(I) Chemistry as Exemplified by Gold Phosphine Complexes
Author:
Hamel, Armin
Year:
2002
Document type:
Dissertation
Faculty/School:
Fakultät für Chemie
Advisor:
Schmidbaur, Hubert (Prof. Dr.)
Referee:
Schmidbaur, Hubert (Prof. Dr.); Nitsch, Walter (Prof. Dr.)
Format:
Text
Language:
de
Subject group:
CHE Chemie
Keywords:
Gold(I) ; Oligomerisierung; Metall-Metall-Kontake; Haloniumsalze; Sulfoximine
Translated keywords:
gold(I) ; oligomerization; metal-metal contact; haloniumsalts ; sulfoximines
Controlled terms:
Goldkomplexe ; Phosphine; Oligomerisation
TUM classification:
CHE 330d; CHE 369d; CHE 612d
Abstract:
Die neuartigen Bindungsbeziehungen zwischen Metallatomen mit formal abgeschlossenen Elektronenschalen sind von aktuellem Interesse. In den jetzt entwickelten Systemen dienen Halonium- atome als Zentren für mehrkernige Goldcluster, deren Aggregation von der Natur der Gegenionen mitbestimmt wird. Ähnliche Oligomerisierungen über Metall-Metall-Kontake wurden auch bei Sulfoximinen beobachtet.
Translated abstract:
Novel bonding relationships between formally closed-shell metal atoms are of current interest. In the system reported here, halonium atoms serve as centres for polymetallic gold clusters, the aggregation of which is dependent also on the nature of the counterion. Similar oligomerizations through metal-metal contacts were also observed with sulfoximines.
Publication :
Universitätsbibliothek der TU München
WWW:
https://mediatum.ub.tum.de/?id=601223
Date of submission:
26.11.2001
Oral examination:
07.01.2002
File size:
8589098 bytes
Pages:
158
Urn (citeable URL):
https://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:91-diss2002010707028
Last change:
06.06.2007
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