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Title:

Synthesis and Catalytic Applications of ansa Compounds with Cycloalkyl Moieties as Bridging Units: A Comparative Study

Document type:
Journal Article
Author(s):
Capape, A.; Raith, A.; Herdtweck, E.; Cokoja, M.; Kuhn, F. E.
Abstract:
The molybdenum and tungsten compounds (Moeta(5)-C(5)H(5)[CH(CH(2))(n)]-eta(1)-CH(CO)(3)) and (Weta(5)-C(5)H(4)[CH(CH(2))(3)]-eta(1)-CH(CO)(3)) (2a, 3a n=3; 2b, 3b n=4; 2c, 3c n=5; 2d, 3d n=6) were synthesized by reacting the spiro-bicyclic compounds 1a-d with the complex [M(CO)(3)(tach)] (M=molybdenum, tungsten; tach=.,3,5-trimethylhexahydro-1,3,5-triazine). NMR spectroscopy, as well as X-ray diffraction studies, confirm the formation of an intramolecular ansa bridge. The complexes display a...     »
Congress title:
ISI Document Delivery No.: 564RZ Times Cited: 12 Cited Reference Count: 80 Capape, Alejandro Raith, Alexander Herdtweck, Eberhardt Cokoja, Mirza Kuehn, Fritz E. Cokoja, Mirza/B-6906-2009; Kuhn, Fritz/A-3113-2010 12 Wiley-v c h verlag gmbh Weinheim
Journal title:
Advanced Synthesis & Catalysis
Year:
2010
Journal volume:
352
Journal issue:
2-3
Pages contribution:
547-556
Fulltext / DOI:
doi:10.1002/adsc.200900708
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