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Titel:

Tortuosity Determination of Battery Electrodes and Separators by Impedance Spectroscopy

Dokumenttyp:
Zeitschriftenaufsatz
Autor(en):
Landesfeind J., Hattendorff J., Ehrl A., Wall W.A., Gasteiger H.A.
Abstract:
Lithium ion battery performance at high charge/discharge rates is largely determined by the ionic resistivity of an electrode or separator which are filled with electrolyte. Key to understand and to model ohmic losses in porous battery components are porosity as well as tortuosity. In the first part, we use impedance spectroscopy measurements in a new experimental setup to obtain the tortuosities and MacMullin numbers of some commonly separators, demonstrating experimental errors of < 8%. In the second part, we present impedance measurements of electrodes in symmetric cells using a blocking electrode configuration, which is obtained by using a non-intercalating electrolyte. The effective ionic resistivity of the electrode can be fit with a transmission-line model, allowing us to quantify the porosity dependent MacMullin numbers and tortuosities of electrodes with different active materials and different conductive carbon content. Best agreement between the transmission-line model and the impedance data is found when constant-phase elements rather than simple capacitors are used.
Dewey Dezimalklassifikation:
620 Ingenieurwissenschaften
Zeitschriftentitel:
Journal of the Electrochemical Society
Jahr:
2016
Band / Volume:
163
Quartal:
2. Quartal
Heft / Issue:
7
Seitenangaben Beitrag:
A1373-A1387
Sprache:
en
Volltext / DOI:
doi:10.1149/2.1141607jes
Status:
Verlagsversion / published
Eingereicht (bei Zeitschrift):
03.03.2016
Angenommen (von Zeitschrift):
08.04.2016
Publikationsdatum:
28.04.2016
Semester:
SS 16
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