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Titel:

The efficiency of driving chemical reactions by a physical non-equilibrium is kinetically controlled

Dokumenttyp:
Zeitschriftenaufsatz
Autor(en):
Göppel, Tobias; Palyulin, Vladimir V.; Gerland, Ulrich
Abstract:
An out-of-equilibrium physical environment can drive chemical reactions into thermodynamically unfavorable regimes. Under prebiotic conditions such a coupling between physical and chemical non-equilibria may have enabled the spontaneous emergence of primitive evolutionary processes. Here, we study the coupling efficiency within a theoretical model that is inspired by recent laboratory experiments, but focuses on generic effects arising whenever reactant and product molecules have different trans...     »
Zeitschriftentitel:
Physical chemistry chemical physics : PCCP
Jahr:
2016
Band / Volume:
18
Heft / Issue:
30
Seitenangaben Beitrag:
20135-20143
Volltext / DOI:
doi:10.1039/c6cp01034b
Verlag / Institution:
Royal Society of Chemistry (RSC)
Print-ISSN:
1463-9076
E-ISSN:
1463-9084
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