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Title:

Preferential oxidation of carbon monoxide adsorbed on Pd submonolayer films deposited on Pt(1 0 0)

Author(s):
Arenz, M.; Stamenkovic, V.; Ross, P. N.; Markovic, N. M.
Abstract:
The electrochem. behavior of palladium modified Pt(100) in perchloric acid soln. was studied by cyclic voltammetry, CO bulk oxidn. and in-situ Fourier transform IR (FTIR) spectroscopy. FTIR spectra on Pd submonolayers reveal that at low potentials (≈0.4 V) Pd-bounded CO is oxidized preferentially, whereas at the same time the Pt-CO oxidn. rate is rather slow. [on SciFinder(R)]
Keywords:
Adsorbed substances Cyclic voltammetry Oxidation (preferential oxidn. of carbon monoxide adsorbed on Pd submonolayer films deposited on Pt(100)) carbon monoxide electrooxidn palladium platinum electrode
Congress title:
CAN 140:66607 72-2 Electrochemistry Lawrence Berkeley National Laboratory, Materials Science Division, University of California, Berkeley, CA, USA. Journal 1388-2481 7601-90-3 (Perchloric acid) Role: NUU (Other use, unclassified), USES (Uses) (electrolyte; preferential oxidn. of carbon monoxide adsorbed on Pd submonolayer films deposited on Pt(100)); 630-08-0 (Carbon monoxide) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (preferential oxidn. of...     »
Journal title:
Electrochem. Commun.
Year:
2003
Journal volume:
5
Journal issue:
9
Pages contribution:
809-813
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