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Title:

Infrared Spectroscopy of Gas-Phase M+(CO2)n (M = Co, Rh, Ir) Ion–Molecule Complexes

Document type:
Zeitschriftenaufsatz
Author(s):
Iskra, Andreas; Gentleman, Alexander S.; Kartouzian, Aras; Kent, Michael J.; Sharp, Alastair P.; Mackenzie, Stuart R.
Abstract:
The structures of gas-phase M+(CO2)n (M = Co, Rh, Ir; n = 2–15) ion–molecule complexes have been investigated using a combination of infrared resonance-enhanced photodissociation (IR-REPD) spectroscopy and density functional theory. The results provide insight into fundamental metal ion–CO2 interactions, highlighting the trends with increasing ligand number and with different group 9 ions. Spectra have been recorded in the region of the CO2 asymmetric stretch around 2350 cm–1 using the inert me...     »
Journal title:
The Journal of Physical Chemistry A
Year:
2016
Journal volume:
121
Year / month:
2016-12
Quarter:
4. Quartal
Month:
Dec
Journal issue:
1
Pages contribution:
133-140
Fulltext / DOI:
doi:10.1021/acs.jpca.6b10902
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