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Title:

Imaging the photodissociation dynamics of neutral metal clusters: copper dimer, Cu2, and copper oxide, CuO

Author(s):
Parry, Imogen S.; Hermes, Alexander C.; Kartouzian, Aras; Mackenzie, Stuart R.
Abstract:
The spectroscopy and UV photodissociation dynamics of Cu2 and CuO have been studied using a combination of one- and two-colour excitation and velocity map imaging. Resonant excitation of Cu2via the J ? X 1[capital Sigma]g+ transition leads to significant fragmentation which is interpreted in terms of a combination of direct dissociation of Cu2+ 2[capital Pi] produced in the resonant two-photon ionization process and dissociation of excited Cu2 states above the ionization threshold. By fitting of...     »
Journal title:
Phys. Chem. Chem. Phys.
Year:
2014
Journal volume:
16
Journal issue:
2
Pages contribution:
458-466
Fulltext / DOI:
doi:10.1039/C3CP53214C
Publisher:
The Royal Society of Chemistry
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