Schmidt, Andrea; Hollering, Manuela; Han, Jiaying; Casini, Angela; Kühn, Fritz E.
Titel:
Self-assembly of highly luminescent heteronuclear coordination cages
Abstract:
Exo-functionalized Pd2L4 cage compounds with attached Ru(ii) pyridine complexes were prepared via coordination-driven self-assembly. Unlike most of the previously reported palladium(ii) cages, one of these metallocages exhibits an exceptionally high quantum yield of 66{%}. The presented approach is promising to obtain luminescent coordination complexes for various applications.