Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation

Titel:: Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation
Dokumenttyp:: Article
Autor(en):: Huber, Stefan; Cokoja, Mirza; Kuehn, Fritz E.
Abstract:: Various polymers, fine chemicals, pharmaceuticals, food additives and flavor & fragrance compounds are based on epoxide intermediates. This historical perspective covers the landmarks of molecular transition metal catalysts for olefin epoxidation. The historic developments of Mo and V catalysts, methyltrioxorhenium and both Sharpless and Jacobsen asymmetric epoxidation are covered and an outlook on new upcoming systems is given. (C) 2013 Elsevier B. V. All rights reserved.
Stichworte:: Transition metal catalyst; Epoxidation; Asymmetric epoxidation; Review
Zeitschriftentitel:: JOURNAL OF ORGANOMETALLIC CHEMISTRY
Jahr:: 2014
Band / Volume:: 751
Monat:: FEB 1
Heft / Issue:: SI
Seitenangaben Beitrag:: 25-32
Sprache:: English
Volltext / DOI:: doi:10.1016/j.jorganchem.2013.07.016
Verlag / Institution:: ELSEVIER SCIENCE SA
Print-ISSN:: 0022-328X
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