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- Title:
Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states
- Author(s):
- Wang, Yi-Hsieh; Teranishi, Y.; Mineo, H.; Chao, S. D.; Selzle, H. L.; Neusser, H. J.; Schlag, E. W.; Lin, S. H.
- Abstract:
- A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approxn. as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calcns. of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diat. mol. as an example. [on SciFinder(R)]
- Congress title:
- 73 Optical, Electron, and Mass Spectroscopy and Other Related Properties Institute of Applied Mechanics, National Taiwan University, Taipei, Taiwan. Journal 0009-2614
- Journal title:
- Chem. Phys. Lett.
- Year:
- 2010
- Journal volume:
- 486
- Journal issue:
- 4-6
- Pages contribution:
- 104-109
- Fulltext / DOI:
- doi:10.1016/j.cplett.2009.12.092
BibTeX
Occurrences:
- mediaTUM GesamtbestandEinrichtungenSchools TUM School of Natural SciencesDepartmentsChemistryLehrstuhl für Physikalische Chemie (Prof. Heiz)current_papersAG Prof. Heizfrom_2004 [1342628]2010