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Title:

Infra-red spectroscopy of size selected Au25, Au38 and Au144 ligand protected gold clusters

Author(s):
Farrag, Mostafa; Tschurl, Martin; Dass, Amala; Heiz, Ulrich
Abstract:
Through the discovery of ligand protected metal clusters with cores of a precise no. of atoms, the exploration of the third dimension of the periodic table for fundamental research and also for applications has become less remote. So far, the exact no. of metal atoms in the core has been detd. unambiguously only using mass spectrometry and single crystal X-ray diffraction. Gold clusters protected by 2-phenylethanethiol ligands, for instance, show distinct magic nos. that correspond to either ele...     »
Congress title:
Inorganic Chemicals and Reactions
Journal title:
Phys. Chem. Chem. Phys.
Year:
2013
Journal volume:
15
Journal issue:
30
Pages contribution:
12539-12542
Fulltext / DOI:
doi:10.1039/c3cp51406d
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