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- Title:
Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene
- Document type:
- Journal Article
- Author(s):
- Forster, T.; Schunk, S. A.; Jentys, A.; Lercher, J. A.
- Abstract:
- Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.
- Congress title:
- ISI Document Delivery No.: 728HL Times Cited: 3 Cited Reference Count: 23 Foerster, Tobias Schunk, Stephan A. Jentys, Andreas Lercher, Johannes A. Jentys, Andreas/D-4622-2009 Jentys, Andreas/0000-0001-5877-5042 3 Royal soc chemistry Cambridge
- Journal title:
- Chemical Communications
- Year:
- 2011
- Journal volume:
- 47
- Journal issue:
- 11
- Pages contribution:
- 3254-3256
- Fulltext / DOI:
- doi:10.1039/c0cc05050d
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