This thesis focuses on the on-surface synthesis of 2D conjugated organometallic networks on partially iodine-passivated Au(111) surfaces (I-Au(111)). Utilizing I-Au(111) promoted the formation of highly regular 2D organogold networks as opposed to bare Au(111). Additionally, self-assembly of supramolecular monolayers at liquid-solid interfaces was explored on I-Au(111). As a result, I-Au(111) has proven to be a suitable alternative substrate with a significant influence on polymorphism and thermodynamic stability.
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This thesis focuses on the on-surface synthesis of 2D conjugated organometallic networks on partially iodine-passivated Au(111) surfaces (I-Au(111)). Utilizing I-Au(111) promoted the formation of highly regular 2D organogold networks as opposed to bare Au(111). Additionally, self-assembly of supramolecular monolayers at liquid-solid interfaces was explored on I-Au(111). As a result, I-Au(111) has proven to be a suitable alternative substrate with a significant influence on polymorphism and therm...
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