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Bartlett, S. A.; Cibin, G.; Dent, A. J.; Evans, J.; Hanton, M. J.; Reid, G.; Tooze, R. P.; Tromp, M.
Sc(III) complexes with neutral N-3- and SNS-donor ligands - a spectroscopic study of the activation of ethene polymerisation catalysts
Scandium trichloride complexes with tridentate N3- and S2N-donor ligands (L3) have been synthesised and characterised by IR, 1H, 13C{1H} and 45Sc NMR spectroscopy, microanalysis, and solid state and solution XAFS spectroscopy. Catalytic testing of a subset of these complexes with ethene has been undertaken in chlorobenzene with MMAO-3A and PMAO-IP at 60 °C and 40 bar ethene, giving low activity ethene polymerisation. The reactions of these complexes with MeLi and AlMe3 were studied by 1H, 13C{1H...    »
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ISI Document Delivery No.: 071TN Times Cited: 0 Cited Reference Count: 43 Bartlett, Stuart A. Cibin, Giannantonio Dent, Andrew J. Evans, John Hanton, Martin J. Reid, Gillian Tooze, Robert P. Tromp, Moniek Evans, John/A-4800-2013; Reid, Gillian/B-9110-2009 Evans, John/0000-0003-3290-7785; Epsrc [ep/032463/1] We thank the EPSRC (EP/032463/1) for support, and Diamond Light Source Ltd for access to the synchrotron facilities (under experiment SP7232-1). Sasol Technology Pty are thanked for permiss...    »
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Dalton Transactions
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