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Author(s):
Arenz, M.; Stamenkovic, V.; Schmidt, T. J.; Wandelt, K.; Ross, P. N.; Markovic, N. M. 
Title:
The electro-oxidation of formic acid on Pt-Pd single crystal bimetallic surfaces 
Abstract:
The interrelationship between the macroscopic kinetic rate of HCOOH oxidn. in 0.1 M HClO4 soln. and the morphol./compn. of the electrode is studied on Pt(111) modified by Pd (denoted hereafter as the Pt(111)-PdxML system, 0 < x < 1) and on Pt-Pd bulk single crystal alloy surfaces (denoted hereafter as the PtPdxat 
Keywords:
Chemically modified electrodes (electrooxidn. of formic acid on Pt(111) modified by Pd single crystal bimetallic surfaces in HClO4 soln.) Oxidation kinetics (for electrooxidn. of formic acid on Pt(111) modified by Pd single crystal bimetallic surfaces in HClO4 soln.) IR spectra (of HCOOH soln. in HClO4 during electrolytic polarization with bare Pt(111), PtPd alloy and Pt with Pd deposited electrodes) Simulation and Modeling (of bare Pt(111), PtPd alloy and Pt with Pd deposited electrode surfaces...    »
 
Congress title:
CAN 140:66614 72-2 Electrochemistry Lawrence Berkeley National Laboratory, Materials Science Division, University of California, Berkeley, CA, USA. Journal 1463-9076 7440-05-3 (Palladium) Role: CAT (Catalyst use), USES (Uses) (electrooxidn. of formic acid on Pt(111) modified by Pd single crystal bimetallic surfaces in HClO4 soln.); 7440-06-4 (Platinum) Role: CAT (Catalyst use), DEV (Device component use), USES (Uses) (electrooxidn. of formic acid on Pt(111) modified by Pd single crystal bimetal...    »
 
Journal title:
Phys. Chem. Chem. Phys. 
Year:
2003 
Journal volume:
Journal issue:
19 
Pages contribution:
4242-4251