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Dokumenttyp:
Zeitschriftenaufsatz 
Autor(en):
Tschurl, Martin; Boesl, Ulrich 
Titel:
IR-photodissociation and photodetachment spectroscopy of Cl− · (NH3)x (IR: 
Abstract:
Complexes of ammonia mols. and one chloride ion have been studied by photodetachment and IR-photodissocn. spectroscopy. For the smallest anionic complex, the stabilization energy with respect to the bare chloride ion and vibrational frequencies have been detd. Two bands showed a splitting due to rotational branches, which could be represented by simulation. Rotational consts. obtained by former ab initio calcns. are confirmed and rotational consts. of a vibrationally excited state are supplied....    »
 
Stichworte:
Cluster structure Electron photodetachment Excited vibrational state IR photolysis IR spectra Molecular rotation Stabilization energy Vibrational excitation Vibrational excitation Vibrational frequency (IR-photodissocn. and photodetachment spectroscopy of Cl--NH3 clusters) chloride ammonia cluster IR photodissocn photodetachment spectroscopy IR spectra rotational const chloride ammonia cluster 
Kongresstitel:
CAN 149:139578 74-1 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes Technical University of Munich, Chemistry Department, Garching, Germany. Journal 0009-2614 152309-82-5; 1036357-29-5; 1036357-32-0; 1036357-34-2 Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (IR-photodissocn. and photodetachment spectroscopy of Cl--NH3 clusters) 
Zeitschriftentitel:
Chem. Phys. Lett. 
Jahr:
2008 
Band / Volume:
456 
Heft / Issue:
4-6 
Seitenangaben Beitrag:
150-155