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Autor(en):
Harding, C. J.; Kunz, Sebastian; Habibpour, Vahideh; Heiz, Ulrich 
Titel:
Microkinetic simulations of the oxidation of CO on Pd based nanocatalysis: a model including co-dependent support interactions 
Abstract:
The catalysed oxidation of CO using mass-selected Pd(13) clusters supported on thin MgO films was modelled using a microkinetic simulation of the reaction. The model of the system includes reverse spill-over calculations which were intrinsically incorporated into the formulation of the kinetics. The spill-over model is based on a capture-zone approach including a co-dependence on the variables of the kinetic equations. The experimental values were determined using dual pulsed-molecular beam meas...    »
 
Kongresstitel:
Lehrstuhl fur Physikalische Chemie, Technische Universitat Munchen, Garching, Germany. 1463-9076 FIELD Electronic Internat.Standard Doc. Number: England: United Kingdom Journal; Article; (JOURNAL ARTICLE); (RESEARCH SUPPORT, NON-U.S. GOV'T) 
Zeitschriftentitel:
Phys Chem Chem Phys 
Jahr:
2008 
Band / Volume:
10 
Heft / Issue:
38 
Seitenangaben Beitrag:
5875-81