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Document type:
Journal Article 
Author(s):
Peng, B. X.; Zhao, C.; Kasakov, S.; Foraita, S.; Lercher, J. A. 
Title:
Manipulating Catalytic Pathways: Deoxygenation of Palmitic Acid on Multifunctional Catalysts 
Abstract:
The mechanism of the catalytic reduction of palmitic acid to n-pentadecane at 260 degrees C in the presence of hydrogen over catalysts combining multiple functions has been explored. The reaction involves rate-determining reduction of the carboxylic group of palmitic acid to give hexadecanal, which is catalyzed either solely by Ni or synergistically by Ni and the ZrO2 support. The latter route involves adsorption of the carboxylic acid group at an oxygen vacancy of ZrO2 and abstraction of the al...    »
 
Congress title:
ISI Document Delivery No.: 123NZ Times Cited: 2 Cited Reference Count: 28 Peng, Baoxiang Zhao, Chen Kasakov, Stanislav Foraita, Sebastian Lercher, Johannes A. EADS Deutschland GmbH; Technische Universitat Munchen We appreciate financial support from EADS Deutschland GmbH. This work was also partially supported by the Technische Universitat Munchen in the framework of the European Graduate School on Sustainable Energy. The authors would like to thank X. Hecht for performing the BET measurements...    »
 
Journal title:
Chemistry-a European Journal 
Year:
2013 
Journal volume:
19 
Journal issue:
15 
Pages contribution:
4732-4741 
Fulltext / DOI: