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Document type:
Journal Article 
Author(s):
Peng, B. X.; Zhao, C.; Mejia-Centeno, I.; Fuentes, G. A.; Jentys, A.; Lercher, J. A. 
Title:
Comparison of kinetics and reaction pathways for hydrodeoxygenation of C-3 alcohols on Pt/Al2O3 
Abstract:
The catalytic hydrodeoxygenation of C-3 alcohols (1- and 2-propanol, 1,2- and 1,3-propanediol, and glycerol) on Pt/Al2O3 has been mechanistically explored in the aqueous phase. Dehydrogenation on Pt and dehydration on alumina are the main elementary reaction pathways. In water, carbon-carbon bond cleavage for alcohols with terminal hydroxyl groups occurs via decarbonylation of aldehydes (generated by dehydrogenation of alcohols) and decarboxylation of acids, the latter being formed by disproport...    »
 
Congress title:
ISI Document Delivery No.: 903OE Times Cited: 9 Cited Reference Count: 35 Peng, Baoxiang Zhao, Chen Mejia-Centeno, Isidro Fuentes, Gustavo A. Jentys, Andreas Lercher, Johannes A. Jentys, Andreas/D-4622-2009; Kang, Zhai/G-8010-2012 Jentys, Andreas/0000-0001-5877-5042; European Union [NMP2-CT-2005-515792-2]; Technische Universitat Munchen in the framework of the European Graduate School for Sustainable Energy; CONACYT (Mexico); Alexander von Humboldt Stiftung (Germany); Alexander von Humbold...    »
 
Journal title:
Catalysis Today 
Year:
2012 
Journal volume:
183 
Journal issue:
Pages contribution:
3-9