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Document type:
Journal Article 
Author(s):
Norder, A.; Warren, S. A.; Herdtweck, E.; Huber, S. M.; Bach, T. 
Title:
Diastereotopos-Differentiation in the Rh-Catalyzed Amination of Benzylic Methylene Groups in the alpha-Position to a Stereogenic Center 
Abstract:
The diastereoselectivity of the Rh-catalyzed C-H amination was examined with 18 chiral open-chain substrates, which bear a benzylic methylene group in the alpha-position to a stereogenic center (-CHMeX), and with four chiral cyclic tetralins, in which the stereogenic center was positioned at carbon atom C2. The C-H amination was performed using trichloroethoxysulfonyl-substituted amine (H(2)NTces) as the nitrogen source, a diacyloxyiodobenzene as the oxidant, and bis[rhodium(alpha,alpha,alpha',a...    »
 
Congress title:
ISI Document Delivery No.: 988JT Times Cited: 3 Cited Reference Count: 57 Noerder, Anike Warren, Sarah A. Herdtweck, Eberhardt Huber, Stefan M. Bach, Thorsten Huber, Stefan/F-7660-2011 Deutsche Forschungsgemeinschaft [Ba 1372-12]; TUM Graduate School; Fonds der Chemischen Industrie for a Liebig fellowship This project was supported by the Deutsche Forschungsgemeinschaft (Ba 1372-12) and by the TUM Graduate School. S.M.H. acknowledges the Fonds der Chemischen Industrie for a Liebig fellowship....    »
 
Journal title:
Journal of the American Chemical Society 
Year:
2012 
Journal volume:
134 
Journal issue:
32 
Pages contribution:
13524-13531 
Fulltext / DOI: