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Document type:
Journal Article 
Author(s):
Kremleva, A.; Zhang, Y.; Shor, A. M.; Kruger, S.; Joseph, C.; Raditzky, B.; Schmeide, K.; Sachs, S.; Bernhard, G.; Rosch, N. 
Title:
Uranyl(VI) Complexation by Sulfonate Ligands: A Relativistic Density Functional and Time-Resolved Laser-Induced Fluorescence Spectroscopy Study 
Abstract:
To study the role of sulfonate functional groups of humic substances in uranyl(VI) complexation, all-electron density functional calculations and time-resolved laser-induced fluorescence spectroscopy (TRLFS) were applied using small sulfonate ligands as models. A thiolate ligand was explored for comparison. As in an earlier experiment, 4-hydroxybenzenesulfonic acid (HBSA) and benzenesulfonic acid (BSA) were examined and compared to methylsulfonic acid (MSA). Structural parameters as well as ener...    »
 
Congress title:
ISI Document Delivery No.: 978IK Times Cited: 1 Cited Reference Count: 64 Kremleva, Alena Zhang, Yun Shor, Aleksey M. Krueger, Sven Joseph, Claudia Raditzky, Bianca Schmeide, Katja Sachs, Susanne Bernhard, Gert Roesch, Notker Kremleva, Alena/K-7309-2012 German Federal Ministry of Economics and Technology [02E10186, 02E10156]; Fonds der Chemischen Industrie (Germany) C. J. would like to thank Gerhard Geipel and Stephan Weiss for technical support and helpful discussions. This work was supported...    »
 
Journal title:
European Journal of Inorganic Chemistry 
Year:
2012 
Journal issue:
22 
Pages contribution:
3636-3644 
Fulltext / DOI: