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Dokumenttyp:
Journal Article
Autor(en):
Riederer, S. K. U.; Bechlars, B.; Herrmann, W. A.; Kuhn, F. E.
Titel:
Chiral N-heterocyclic biscarbenes based on 1,2,4-triazole as ligands for metal-catalyzed asymmetric synthesis
Abstract:
A facile and straightforward synthetic procedure for the preparation of new chiral bis-1,2,4-triazolium salts and their corresponding rhodium(I) biscarbene complexes are reported. It is widely applicable for the synthesis of 1,2,4-triazolium salts. The new chiral biscarbenes represent promising ligands for transition metal-catalyzed asymmetric syntheses. Their first successful application is demonstrated by the rhodium-catalyzed hydrogenation of dimethylitaconate and methyl-2-acetamidoacrylate w...     »
Kongresstitel:
ISI Document Delivery No.: 697YV Times Cited: 7 Cited Reference Count: 33 Riederer, Stephanie K. U. Bechlars, Bettina Herrmann, Wolfgang A. Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010; Herrmann, Wolfgang/A-3588-2010 Margarete Ammon Stiftung This work was generously supported by the Margarete Ammon Stiftung (Ph.D. grant for S.K.U.R). 7 Royal soc chemistry Cambridge
Zeitschriftentitel:
Dalton Transactions
Jahr:
2011
Band / Volume:
40
Heft / Issue:
1
Seitenangaben Beitrag:
41-43
Volltext / DOI:
doi:10.1039/c0dt00724b
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