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- Document type:
- Journal Article
- Author(s):
- Rach, S. F.; Herdtweck, E.; Kuhn, F. E.
- Title:
- Molecular Structure and Solution Behavior of a Benzonitrile Ligated Silver(I) Complex Ag(PhCN)(2) B(C6F5)(4)
- Abstract:
- The bis(benzonitrile) complex [Ag(PhCN)(2)][B(C6F5)(4)] is synthesized from its tetra(acetonitrile) ligated congener. X-ray diffraction studies were conducted to compare the bond lengths and angles of the complex in regard with those of other nitrile ligated silver cations with weakly coordinating anions. Vibrational spectra of the solid complex and in (concentrated) benzonitrile solution reveal differences in the strength of benzonitrile-silver ion interactions.
- Congress title:
- ISI Document Delivery No.: 750FN Times Cited: 0 Cited Reference Count: 18 Rach, Silvana F. Herdtweck, Eberhardt Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010 International Graduate School of Science and Engineering (IGSSE); BASF SE, Ludwigshafen This work was supported by the International Graduate School of Science and Engineering (IGSSE, Ph. D. grant to SFR) and BASF SE, Ludwigshafen (Dr. Klaus Muhlbach, Dr. Hannah Konig). Prof. Dr. Janos Mink (Hungarian Academy of Sciences) is also acknowledged fo... »
- Journal title:
- Zeitschrift Fur Anorganische Und Allgemeine Chemie
- Year:
- 2011
- Journal volume:
- 637
- Journal issue:
- 5
- Pages contribution:
- 499-501
- Fulltext / DOI:
- doi:10.1002/zaac.201000408
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