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Document type:
Journal Article 
Author(s):
Rach, S. F.; Herdtweck, E.; Kuhn, F. E. 
Title:
A straightforward synthesis of cationic nitrile ligated transition metal complexes with the B(C6F5)(4) (-) anion 
Abstract:
Nitrile ligated transition metal complexes bearing polyfluorinated tetra(aryl) borates as counter anions are highly active initiators/mediators for various polymerization reactions. However, the methods for their preparation are still far too inefficient for widespread use in applied research or in industry. Accordingly, an improved synthesis for two of the most promising species in this assemblage of complexes, namely [Cu(C6H5CN)(5)][B(C6F5)(4)](2) and [Zn(CH3CN)(4/6)][B(C6F5)(4)](2), has been...    »
 
Congress title:
ISI Document Delivery No.: 756NN Times Cited: 1 Cited Reference Count: 58 Rach, Silvana F. Herdtweck, Eberhardt Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010 International Graduate School of Science and Engineering (IGSSE) S. F. R. thanks the International Graduate School of Science and Engineering (IGSSE) for a Ph.D grant. E. H. thanks Dr. Bernhard Wahl for his assistance during the X-ray experiments. 1 Elsevier science sa Lausanne 
Journal title:
Journal of Organometallic Chemistry 
Year:
2011 
Journal volume:
696 
Journal issue:
Pages contribution:
1817-1823