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Document type:
Journal Article 
Author(s):
Capape, A.; Raith, A.; Herdtweck, E.; Cokoja, M.; Kuhn, F. E. 
Title:
Synthesis and Catalytic Applications of ansa Compounds with Cycloalkyl Moieties as Bridging Units: A Comparative Study 
Abstract:
The molybdenum and tungsten compounds (Moeta(5)-C(5)H(5)[CH(CH(2))(n)]-eta(1)-CH(CO)(3)) and (Weta(5)-C(5)H(4)[CH(CH(2))(3)]-eta(1)-CH(CO)(3)) (2a, 3a n=3; 2b, 3b n=4; 2c, 3c n=5; 2d, 3d n=6) were synthesized by reacting the spiro-bicyclic compounds 1a-d with the complex [M(CO)(3)(tach)] (M=molybdenum, tungsten; tach=.,3,5-trimethylhexahydro-1,3,5-triazine). NMR spectroscopy, as well as X-ray diffraction studies, confirm the formation of an intramolecular ansa bridge. The complexes display a...    »
 
Congress title:
ISI Document Delivery No.: 564RZ Times Cited: 12 Cited Reference Count: 80 Capape, Alejandro Raith, Alexander Herdtweck, Eberhardt Cokoja, Mirza Kuehn, Fritz E. Cokoja, Mirza/B-6906-2009; Kuhn, Fritz/A-3113-2010 12 Wiley-v c h verlag gmbh Weinheim 
Journal title:
Advanced Synthesis & Catalysis 
Year:
2010 
Journal volume:
352 
Journal issue:
2-3 
Pages contribution:
547-556 
Fulltext / DOI: