Capsoplexes: encapsulating complexes via guest recognition
Abstract:
A new dinuclear Ni-NHC complex is able to selectively recognise and self-assemble with guests via tennis-ball like encapsulation, exemplarily demonstrated employing halides. Addition of chloride or bromide leads to the formation of capsules with small cavities which are stabilised through non-classical hydrogen bonds and Coulomb interactions between the anion and the metal centres.
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