Benutzer: Gast  Login
Dokumenttyp:
Journal Article 
Autor(en):
Putzien, S.; Louis, E.; Nuyken, O.; Kuhn, F. E. 
Titel:
PtO2 as a "self-dosing" hydrosilylation catalyst 
Abstract:
The reaction behavior of PtO2 in the hydrosilylation of n-octene with heptamethyltrisiloxane was examined. PtO2 proved to be a highly active and selective hydrosilylation catalyst precursor reaching turn-over frequencies in the order of magnitude of 10(5) h(-1). In contrast to usual homogeneous catalysts PtO2 dissolves only to a small degree after reaction with silane. The un-reacted solid catalyst could be easily separated from the reaction mixture by simple decantation or filtration and could...    »
 
Kongresstitel:
ISI Document Delivery No.: 915YG Times Cited: 1 Cited Reference Count: 21 Putzien, Sophie Louis, Eckhart Nuyken, Oskar Kuehn, Fritz E. Kuhn, Fritz/A-3113-2010 TUM graduate school Financial support of this work by the TUM graduate school is gratefully acknowledged. 1 Royal soc chemistry Cambridge 
Zeitschriftentitel:
Catalysis Science & Technology 
Jahr:
2012 
Band / Volume:
Heft / Issue:
Seitenangaben Beitrag:
725-729