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- Original title:
- Dicarboxylate-bridged Mo2 paddle-wheel complexes as building units for supramolecular coordination polymers
- Translated title:
- Dicarboxylat-verbrückte Mo2-Schaufelrad Komplexe als Bausteine für supramolekulare Koordinationspolymere
- Author:
- Köberl, Mathias
- Year:
- 2012
- Document type:
- Dissertation
- Faculty/School:
- Fakultät für Chemie
- Advisor:
- Kühn, Fritz Elmar (Prof. Dr.)
- Referee:
- Kühn, Fritz Elmar (Prof. Dr.); Hinrichsen, Kai-Olaf (Prof. Dr.)
- Language:
- en
- Subject group:
- CHE Chemie
- Controlled terms:
- Koordinationslehre; Molybdänverbindungen; Supramolekulare Struktur
- TUM classification:
- CHE 334d; CHE 374d; CHE 780d
- Abstract:
- Treatment of [Mo2(L)10][BF4]4 (L = CH3CN) with dicarboxylates in acetonitrile led to several dicarboxylate-bridged macromolecules. By using perfluoroterephthalate and isophthalates (m-bdc-X), square-shaped complex [(L)6Mo2(O2C–C6F4–CO2)]4[BF4]8 and bowl-shaped triangles [(L)6Mo2(m-bdc–X)]3[BF4]6 (X = OH, Br, NH2) were synthesized. Synthesis of 1D and 3D coordination polymers via assembly of molecular building blocks is possible. 1D polymer {[(CH3CH2CN)6Mo2(O2C–C6F4–CO2)]4[BF4]8}n is composed of... »
- Translated abstract:
- Die Reaktion von [Mo2(L)10][BF4]4 (L = CH3CN) mit Dicarboxylaten in Acetonitril führte zu dicarboxylat-verbrückten Makromolekülen wie z. B. dem molekularen Viereck [(L)6Mo2(O2C–C6F4–CO2)]4[BF4]8 und den Dreiecken [(L)6Mo2(m-bdc–X)]3[BF4]6 (m-bdc = isophthalate, X = OH, Br, NH2). Die Synthese von 1D und 3D Koordinationspolymeren aus molekularen Bausteinen ist möglich. 1D Polymer {[(CH3CH2CN)6Mo2(O2C–C6F4–CO2)]4[BF4]8}n besteht aus viereckigen Bausteinen, welche über axiale Positionen durch BF4 An... »
- WWW:
- https://mediatum.ub.tum.de/?id=1116568
- Date of submission:
- 17.10.2012
- Oral examination:
- 05.12.2012
- File size:
- 32763404 bytes
- Pages:
- 142
- Urn (citeable URL):
- https://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:91-diss-20121205-1116568-1-2
- Last change:
- 05.03.2013
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