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- Original title:
- Neue Oligomerisierungsphänomene in der Gold(I)-Chemie am Beispiel der (Phosphan)Gold-Komplexe
- Translated title:
- New Oligomerisation Phenomena in Gold(I) Chemistry as Exemplified by Gold Phosphine Complexes
- Author:
- Hamel, Armin
- Year:
- 2002
- Document type:
- Dissertation
- Faculty/School:
- Fakultät für Chemie
- Advisor:
- Schmidbaur, Hubert (Prof. Dr.)
- Referee:
- Schmidbaur, Hubert (Prof. Dr.); Nitsch, Walter (Prof. Dr.)
- Format:
- Text
- Language:
- de
- Subject group:
- CHE Chemie
- Keywords:
- Gold(I) ; Oligomerisierung; Metall-Metall-Kontake; Haloniumsalze; Sulfoximine
- Translated keywords:
- gold(I) ; oligomerization; metal-metal contact; haloniumsalts ; sulfoximines
- Controlled terms:
- Goldkomplexe ; Phosphine; Oligomerisation
- TUM classification:
- CHE 330d; CHE 369d; CHE 612d
- Abstract:
- Die neuartigen Bindungsbeziehungen zwischen Metallatomen mit formal abgeschlossenen Elektronenschalen sind von aktuellem Interesse. In den jetzt entwickelten Systemen dienen Halonium- atome als Zentren für mehrkernige Goldcluster, deren Aggregation von der Natur der Gegenionen mitbestimmt wird. Ähnliche Oligomerisierungen über Metall-Metall-Kontake wurden auch bei Sulfoximinen beobachtet.
- Translated abstract:
- Novel bonding relationships between formally closed-shell metal atoms are of current interest. In the system reported here, halonium atoms serve as centres for polymetallic gold clusters, the aggregation of which is dependent also on the nature of the counterion. Similar oligomerizations through metal-metal contacts were also observed with sulfoximines.
- Publication :
- Universitätsbibliothek der TU München
- WWW:
- https://mediatum.ub.tum.de/?id=601223
- Date of submission:
- 26.11.2001
- Oral examination:
- 07.01.2002
- File size:
- 8589098 bytes
- Pages:
- 158
- Urn (citeable URL):
- https://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:bvb:91-diss2002010707028
- Last change:
- 06.06.2007
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