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- Autor(en):
- Tschurl, Martin; Boesl, Ulrich
- Titel:
- Photodetachment photoelectron spectroscopy of the weakly bound OClO-center dot H2O complex
- Abstract:
- The weakly bound complex OClO-·H2O and its neutral counterpart are of interest for atm. chem. as well as for studies of microsolvation. Electron affinity and binding energies can be deduced from photodetachment photoelectron spectra of the bare mol. and its H2O complex. Such spectra are presented here. An unusual large binding energy of the anionic cluster of 0.75 eV was found. [on SciFinder(R)]
- Stichworte:
- Binding energy Electron affinity (from photodetachment photoelectron spectroscopy of weakly bound OClO-·H2O complex) Electron photodetachment UV photoelectron spectra (photodetachment photoelectron spectroscopy of weakly bound OClO-·H2O complex) chlorine dioxide monoanion complex water photodetachment UPS binding energy
- Kongresstitel:
- CAN 148:108106 73-6 Optical, Electron, and Mass Spectroscopy and Other Related Properties Chemistry Department, Physical Chemistry, Technical University of Munich, Garching, Germany. Journal 0942-9352 10049-04-4 (Chlorine oxide (ClO2)); 14998-27-7 (Chlorite); 53839-08-0 Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (photodetachment photoelectron spectroscopy of weakly bound OClO-·H2O complex)
- Zeitschriftentitel:
- Z. Phys. Chem. (Muenchen, Ger.)
- Jahr:
- 2007
- Band / Volume:
- 221
- Heft / Issue:
- 5
- Seitenangaben Beitrag:
- 609-618
- Volltext / DOI:
- doi:10.1524/zpch.2007.221.5.609
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