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- Document type:
- Zeitschriftenaufsatz
- Author(s):
- Ketkov, Sergey Y.; Selzle, Heinrich L.; Cloke, F. Geoffrey N.
- Title:
- Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy
- Abstract:
- It's a gas! Mass-analyzed threshold ionization (MATI) spectroscopy provides high-resoln. ionization potentials and low-energy vibrational frequencies of individual conformers of jet-cooled [(η6-PhMe)2Cr]. The signals arising from distinct structural isomers were identified from DFT calcns. and comparison of the [(η6-PhMe)2Cr] and [(η6-1,3-Me2C6H4)(η6-PhH)Cr] spectra (see picture). [on SciFinder(R)]
- Keywords:
- Ionization potential Spectroscopy (direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy) Isomers (rotational direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy) bisarenechromium gaseous rotational isomer mass analyzed threshold ionization spectroscopy
- Congress title:
- CAN 148:23399 80-5 Organic Analytical Chemistry G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia. Journal 1433-7851 33505-50-9 Role: ANT (Analyte), PRP (Properties), ANST (Analytical study) (confomers; direct detection of individual bis(arene) rotational isomers in gas phase by mass-analyzed threshold ionization spectroscopy); 957763-22-3P Role: ANT (Analyte), PRP (Properties), SPN (Synthetic preparation), ANST (Analytical study), PREP... »
- Journal title:
- Angew. Chem., Int. Ed.
- Year:
- 2007
- Journal volume:
- 46
- Journal issue:
- 37
- Pages contribution:
- 7072-7074
- Fulltext / DOI:
- doi:10.1002/anie.200702233
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